What the chart shows
The psychrometric chart (i-d chart in Russian practice, Ramzin chart) relates the properties of moist air at constant pressure: dry-bulb temperature t, relative humidity φ, humidity ratio d (g of moisture per kg of dry air), enthalpy i (kJ per kg of dry air), dew point and wet-bulb temperature. An air state is a point on the chart; any two independent properties fix it. The Russian chart is oblique: lines of constant d are vertical, lines of constant i slope down to the right, and the 0 °C isotherm is horizontal, which uses the plot area fully.
Formulas
- Saturation pressure pws(t) from the Hyland–Wexler equation (ASHRAE Handbook — Fundamentals, 2017, ch. 1) or the Magnus formula: 6.112·exp(17.62·t/(243.12 + t)) hPa over water.
- Vapor partial pressure pv = φ·pws.
- Humidity ratio d = 0.621945·pv / (B − pv), B being the barometric pressure.
- Enthalpy i = 1.006·t + d·(2501 + 1.86·t) kJ/kg of dry air.
- Dew point is the temperature where pws equals pv.
- Wet bulb from the ASHRAE equation linking d, t and the adiabatic saturation temperature.
- Moist air density ρ = (B − pv)/(Rd·T) + pv/(Rv·T).
Processes
- Heating goes up along d = const and φ falls. Cooling goes down the same vertical; once the dew point is reached, the air follows the saturation line and is dehumidified (condensate). Power Q = G·(i₂ − i₁).
- Mixing of two streams: d and i of the mixture are averages weighted by the dry air flows; the mixture point lies on the line between the stream points. If it falls above the saturation line, fog forms.
- Adiabatic humidification (sprays, wetted media) follows i = const: humidity ratio rises, temperature falls, the limit is saturation at the wet-bulb temperature.
Pressure and altitude
A chart is valid for one barometric pressure. At altitude the pressure is lower and the humidity ratio at the same φ is higher, so B is an input here (about 89,900 Pa at 1000 m).
Sources
ASHRAE Handbook — Fundamentals, chapter Psychrometrics; Sonntag D., Advancements in the field of hygrometry, 1990 (Magnus formula); Ramzin L. K., moist air diagram; Russian code SP 60.13330 (heating, ventilation and air conditioning).